Logo image
Organic‐matter sources and stability in kettle‐hole sediments: A combined thermogravimetric and isotopic approach
Journal article   Open access   Peer reviewed

Organic‐matter sources and stability in kettle‐hole sediments: A combined thermogravimetric and isotopic approach

Safdar Bashir, Kai Nils Nitzsche and Zachary Kayler
Agrosystems, geosciences & environment, Vol.9(3), pp.1-13
09/2026

Abstract

Arable land Carbon Carbon 13 Composition Decomposition Forests Isotopes Kettles Land use Mineralization Nitrogen Nitrogen cycle Nitrogen sources Organic matter Sediments Stable isotopes Statistical analysis Temperature Thermal stability Thermogravimetric analysis Carbon Cycle Grasslands
Kettle‐holes are small but biogeochemically active landscape elements that integrate terrestrial inputs and influence carbon and nitrogen cycling. However, the stability and sources of organic matter (OM) in kettle‐hole sediments remain poorly understood. We combined thermogravimetric analysis with stable isotope measurements (δ13C and δ15N) to assess the influence of arable, forest, and grassland land uses on the composition and stability of OM in kettle‐hole sediments of northeastern Germany. Thermal fraction analysis showed broadly similar OM composition among all land‐use types, although some differences were observed. Forest sediments showed highest proportion of Fraction 2 (45.3%), while grassland sediments contained the lowest (38.7%). Grassland sediments also showed a greater proportion of thermally stable fractions (Fractions 4–5: 11:0%) compared with arable (6.9%) and forest sediments (6.0%). δ15N values ranged from −0.3 ± 1.7‰ (Forest) to +3.7 ± 0.3‰ (arable), suggesting contrasting nitrogen sources and/or processing, while δ13C values (−28.7‰ to −28.3‰) showed minimal variations across land uses. Statistical analysis revealed a marginal land‐use effect on OM fractions (p = 0.048), with no significant pairwise differences among land‐use types. The results indicate that differences in OM stability across land uses are subtle and should be interpreted cautiously. The integration of thermal and isotopic approaches provides complementary insights into OM dynamics, although isotopic differentiation in this study was primarily driven by δ15N. Overall, this study highlights the importance of considering both OM stability and source indicators when evaluating sediment carbon dynamics in small landscape features.
url
https://doi.org/10.1002/agg2.70417View
Published (Version of record) Open

Metrics

1 Record Views

Details

Logo image