Experimental and theoretical study of stabilization of delocalized forms of semibullvalenes and barbaralanes by dipolar and polarizable solvents. Observation of a delocalized structure that is lower in free energy than the localized form

W. Daniel Edwards; Maximilian Seefelder; Markus Heubes; Helmut Quast; John R Armantrout; Richard Vaughan Williams; Christopher J Cramer; Alan C Goren; David A Hrovat; Weston Thatcher Borden

doi:10.1021/jo0502089

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Experimental and theoretical study of stabilization of delocalized forms of semibullvalenes and barbaralanes by dipolar and polarizable solvents. Observation of a delocalized structure that is lower in free energy than the localized form

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Experimental and theoretical study of stabilization of delocalized forms of semibullvalenes and barbaralanes by dipolar and polarizable solvents. Observation of a delocalized structure that is lower in free energy than the localized form

W. Daniel Edwards, Maximilian Seefelder, Markus Heubes, Helmut Quast, John R Armantrout, Richard Vaughan Williams, Christopher J Cramer, Alan C Goren, David A Hrovat and Weston Thatcher Borden

Journal of Organic Chemistry, Vol.70(9), pp.3437-3449

2005

DOI: https://doi.org/10.1021/jo0502089

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Title: Experimental and theoretical study of stabilization of delocalized forms of semibullvalenes and barbaralanes by dipolar and polarizable solvents. Observation of a delocalized structure that is lower in free energy than the localized form
Creators: W. Daniel Edwards - Transylvania University
Maximilian Seefelder - Transylvania University
Markus Heubes - Transylvania University
Helmut Quast - University of Idaho
John R Armantrout - University of Idaho
Richard Vaughan Williams - University of Idaho
Christopher J Cramer - Transylvania University
Alan C Goren - Transylvania University
David A Hrovat - University of Washington
Weston Thatcher Borden - University of Idaho
Publication Details: Journal of Organic Chemistry, Vol.70(9), pp.3437-3449
Identifiers: 996631762401851
Academic Unit: Chemistry
Language: English
Resource Type: Journal article