Abstract
This work focused on the factors affecting the effective generation of corona discharge plasma in a honeycomb catalyst reactor. Pd, Co, and Ag were used as the active metal catalysts to investigate the plasma formation and decomposition of ethylene. Unlike the Ag-coated honeycomb catalyst, which resulted in excessive arcing, the Co-coated honeycomb monolith was able to generate stable plasma, but the discharge power was insufficient to decompose ethylene at an acceptable level. The incorporation of a small amount of Pd with Co significantly enhanced the discharge power and the ethylene removal performance. The catalytic activity of the prepared catalyst for the removal of ethylene was evaluated using plasma catalytic oxidation and thermal catalytic oxidation. ANOVA was used to assess the effect of single process factors and their relationships in the plasma process. All the process factors such as specific energy input (SEI), ethylene concentration, and flow rate were found to affect the ethylene conversion, CO2 selectivity, and energy efficiency (EE). Under the optimal conditions, i.e., an SEI of 80 J/L, an ethylene concentration of 20 ppm, and a flow rate of 20 L/min, the ethylene conversion was 85 %, CO2 selectivity was 70 %, and EE was 0.86 g/kW h.
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•Stable corona plasma formation using Co/ZSM-5/monolith and Co-Pd/ZSM-5/monolith.•Bimetallic catalyst shows better catalytic activity than monometallic catalyst.•Ag/ZSM-5/monolith creates numerous arcing and poor plasma formations.•ANOVA with F-test investigates the relationship between the influential factors and NTP reaction activity.