Abstract
Lignocellulosic bio-based materials, such as wood, biocomposites, and natural fibers, exhibit desirable structural properties. This comprehensive review emphasizes the foundational and latest advancements in bioinspired improvement strategies, such as direct mineralization, biomineralization, lignocellulosic nanomaterials, protein-based treatments, and metal-chelating processes. Significant focus was placed on biomimetics, emulating natural protective mechanisms, with discussions on relevant topics including hierarchical mineral deposition, free-radical formation and quenching, and selective metal ion binding, and relating them to lignocellulosic bio-based material property improvements, particularly against fire and fungi. This review evaluates the effectiveness of different bioinspired processes: mineralized and biomineralized composites improve thermal stability, nanocellulose and lignin nanoparticles provide physical, thermal, and chemical barriers, proteins offer biochemical inhibition and mineral templating, and chelators interfere with fungal oxidative pathways while simultaneously improving fire retardancy through selective binding with metal ions. Synergistic approaches integrating various mechanisms could potentially lead to long-lasting and multifunctional protection. This review also highlights the research gaps, challenges, and potential for future applications.